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Sum Parameter – Total Organic Carbon



                                        TOC-4200 – Carryover free TOC determination


            No.  SCA-130-609

                                                                At the outlet of such purification or wastewater
            The  TOC  (Total Organic Carbon)  parameter
            for organic pollution of wastewater can serve       treatment plants, the TOC content of the efflu-
            as an indicator for accurate and efficient con-     ent water is usually less than  50  mg/L.  The
            trol of industrial processes. Using Shimadzu’s      sample  matrices  and measuring  ranges of
            TOC-4200 and switching between measuring            these sample streams thus vary widely. Moni-
            points, up to six sample streams can be moni-       toring these sample streams using a single an-
            tored  –  even in sample  streams of  different     alyzer will place high demands on the instru-
            concentration levels.                               ment and the sampling method used.

            ■ Example: wastewater treatment plant               ■ ISP-Module in the TOC-4200
            In industrial water purification and wastewater     The    ISP   module     (Integrated  Sample
            treatment plants, a  variety of processes are       Pretreatment) is the heart of  the  TOC-4200
            used  to purify wastewaters in  different sub-      series.  It consists of an 8-port  valve and a
            processes (for instance, biological or filtration   syringe  pump. The consistent use of inert
            processes). The TOC sum parameter provides          materials reduces  the  risk of cross-
            important information on  the  remaining or-        contamination.  In addition to automated
            ganic contamination and thus on the efficiency      sample    pretreatment    (acidification  and
            of the treatment plant.                             sparging), the module enables dilution of the

                                                                sample. It is also possible to determine self-
                                                                cleaning sequences for the module as well as
                                                                the sample inlets.











                     Fig.:  Example from paper industry:
                     Four very diverse sample streams
            At the inlet of such plants, TOC concentrations
            of well over 1,000 mg/L as well as high salt                Fig.: ISP-Module TOC-4200 Series
            loads can be expected. Dissolved organic sub-
            stances are decomposed in biological interme-       The automated dilution  function serves not
            diate  stages. Flocculation or precipitation        only for measurement  range extension, but
            agents added at this stage modify the sample        also for matrix reduction. This reduces mainte-
            composition (matrix).                               nance and lowers operating costs.
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