Page 7 - 6_TOC in daily practice
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Sum parameter – Total Organic Carbon



                                        Continuous TOC determination in the

                                        chemical industry
                    SCA-130-603


            The high demand for many different products         be polluted with high  salt loads.  For TOC
            from the chemical industry and the required         determination    in   wastewater,    catalytic
            efficiency  of  the  manufacturing  processes       combustion has become the  method of
            often requires around-the-clock production.         choice based on its higher oxidation potential,
            This results in huge amounts of wastewater.         especially for particles.
            This water mostly originates from flowing
            water bodies.                                       ■ Are high salt loads a problem?
                                                                During thermal catalytic combustion of the
                                                                test  sample,  the  dissolved  salts  crystallize.
                                                                High salt loads can  lead to pollution of the
                                                                catalyst, or even  clogging of the system.
                                                                Maintenance     measures      (for   instance
                                                                exchanging the catalyst) would then be
                                                                required in order to render the instrument
                                                                operational again. Of course, it is desirable to
                                                                keep the maintenance  intervals as long as
                                                                possible.


                                                                ■TOC-4200
            Industrial  wastewaters  must  be  pretreated       The  TOC-4200  offers  various  possibilities  to
            before being discharged into public sewage          keep the maintenance needs for highly
            treatment plants. Direct discharge into water       polluted samples at a minimum.  The TOC-
            bodies  requires an extensive  cleaning             4200 with catalytic combustion at 680 °C is a
            process.  This  is  why  many  large  companies     high-performance analyzer. This temperature
            or industrial parks  operate their own              is lower than the melting point  of sodium
            wastewater treatment plants.                        chloride   and    will,  therefore,  prevent
                                                                deactivation of the active centers of the
            ■    TOC     determination    in   industrial       catalyst  by  a  melt.  The  use  of  a  platinum
            wastewater                                          catalyst  ensures  the  complete  conversion  of
            The TOC content (Total Organic Carbon) is a         the organic compounds to CO 2.  The highly
            measure of the concentration of  organically        sensitive NDIR detector allows small injection
            bound carbon and is  an indication of the           volumes (typically 20 - 50 µL) that reduce the
            pollution  level  by  organic  compounds  in        absolute sample  input onto  the catalyst.  A
            wastewater.  This  is  why  the  TOC  is  often     further reduction  can be achieved using the
            used  in  sewage  treatment  plants  as             integrated dilution function.
            measuring parameter to monitor and optimize
            the treatment process and to calculate
            pollution levels. The matrix in industrial
            effluents can vary greatly and can – prior to
            sewage treatment –
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