Page 186 - Shimadu Consumables Catalog

GC Columns

SH-5 Amine / SH-35 Amine

Dedicated columns for amines and other basic compounds, including alkylamines, diamines, triamines, ethanolamines, and
nitrogen-containing heterocyclics.

SH-5 Amine (Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane)

ID df Temp. Range 15 m 30 m
0.25 µm -60 to 300/315 °C - 227-36282-01
0.25 mm 0.50 µm -60 to 300/315 °C 227-36323-01 227-36283-01
1.00 µm -60 to 300/315 °C 227-36323-02 227-36284-01
1.00 µm -60 to 300/315 °C - 227-36332-02
0.32 mm
1.50 µm -60 to 290/305 °C - 227-36285-01
1.00 µm -60 to 290/305 °C - 227-36286-01
0.53 mm
3.00 µm -60 to 280/295 °C - 227-36287-01

SH-35 Amine (Mid-polarity phase: Crossbond™ 35% diphenyl / 65% dimethyl polysiloxane)
ID df Temp. Range 30 m
0.50 µm 0 to 220 °C 227-36288-01
0.25 mm
1.00 µm 0 to 220 °C 227-36289-01
1.00 µm 0 to 220 °C 227-36290-01
0.32 mm
1.50 µm 0 to 220 °C 227-36291-01
1.00 µm 0 to 220 °C 227-36292-01
0.53 mm
3.00 µm 0 to 220 °C 227-36293-01

Amines & Phenols

Peaks
1. diethylamine
2. pyridine
9 3. morpholine
4
4. phenol
5. aniline
6. 2-chlorophenol
7. diethylenetriamine
8. octylamine
5 9. 1-methyl-2-pyrrolidinone
3 10. 2-nitrophenol
1 2 11. 2,6-dimethylaniline
13 12. nicotine
13. 2-nitroaniline
11
8 Conditions
Column : SH-5 Amine, 30 m, 0.32 mm ID, 1.00 μm
6 10 (P/N: 227-36290-01)
Inj. Vol. : 1 μL split injection of
miscellaneous amines and
7 phenols in water (split ratio: 25:1)
12 On-column conc. : 22 ng
Inj. Temp : 305 °C
Oven Temp : 120 °C to 220 °C at 10 °C/min
Carrier Gas : Hydrogen, linear velocity
38cm/sec. set at 120 °C
Detector Temp : 305 °C
FID sensitivity : 6.4 × 10 AFS
-11
min. 2 4 6 8 10

Pg C-36