Page 157 - Shimadu Consumables Catalog

Capillary Columns
High-Performance Columns

SH-I-5MS
Low-polarity phase: Crossbond™ 5% diphenyl / 95% dimethyl polysiloxane
SH-I-5MS Structure
Tested and guaranteed for ultra-low bleed; improved signal-to-noise ratio for better
sensitivity and mass spectral integrity.
General-purpose columns for semi-volatiles, phenols, amines, residual solvents, drugs of
abuse, pesticides, PCB congeners (e.g., Aroclor mixes), solvent impurities.
Equivalent to USP G27 and G36 phases.
Similar phases: HP-5ms UI, HP-5ms, DB-5, Ultra-2, CP Sil 8 CB, SPB-5, Equity-5

ID df Temp. Range 20 m 25 m 50 m
0.18 µm -60 to 330/350 °C 227-36015-01 − −
0.18 mm 0.30 µm -60 to 330/350 °C 227-36016-01 − −
0.36 µm -60 to 330/350 °C 227-36017-01 − −
0.20 mm 0.33 µm -60 to 330/350 °C − 227-36018-01 227-36018-02
ID df Temp. Range 15 m 30 m 60 m
0.25 µm -60 to 330/350 °C 221-75940-15 221-75940-30 227-36019-01
0.40 µm -60 to 330/350 °C − 227-36020-01 −
0.25 mm
0.50 µm -60 to 330/350 °C 227-36021-01 221-75941-30 221-75942-60
1.00 µm -60 to 330/350 °C 227-36022-01 227-36022-02 227-36022-03
0.25 µm -60 to 330/350 °C 227-36023-01 221-75943-30 227-36023-02
0.32 mm 0.50 µm -60 to 330/350 °C 227-36024-01 221-75944-30 227-36024-02
1.00 µm -60 to 330/350 °C 227-36025-01 227-36025-02 227-36025-03
0.25 µm -60 to 330/350 °C 227-36026-01 227-36026-02 −
0.50 µm -60 to 330/350 °C 227-36027-01 227-36027-02 −
0.53 mm
1.00 µm -60 to 330/350 °C 227-36028-01 227-36028-02 −
1.50 µm -60 to 330/350 °C 227-36029-01 227-36029-02 −

Peaks
GC Multiresidue Pesticide 1. Chloroneb 21. cis-Chlordane
2. Pentachlorobenzene 22. trans-Nonachlor
3. alpha-BHC 23. Chlorfenson (Ovex)
4. Hexachlorobenzene 24. 4,4'-DDE
5. Pentachloroanisole 25. Dieldrin
6. beta-BHC 26. 2,4'-DDD
7. gamma-BHC (Lindane) 27. Endrin
8. delta-BHC 28. Ethylan (Perthane)
9. Endosulfan ether 29. Endosulfan II
10. Heptachlor 30. 4,4'-DDD
11. Pentachlorothioanisole 31. 2,4'-DDT
12. Aldrin 32. cis-Nonachlor
13. 4,4'-Dichlorobenzophenone 33. Endrin aldehyde
14. Fenson 34. 4,4'-Methoxychlor olefin
15. Isodrin 35. Endosulfan sulfate
16. Heptachlor epoxide (Isomer B) 36. 4,4'-DDT
17. Chlorbenside 37. 2,4'-Methoxychlor
18. trans-Chlordane 38. Endrin ketone
19. 2,4'-DDE 39. Tetradifon
20. Endosulfan I 40. Mirex
Conditions
Column : SH-I-5MS, 30 m, 0.25 mm ID,
0.25 um (P/N: 221-75940-30)
Inj. Vol. : 1 μL split (split ratio 50:1)
Inj. Temp : 250 °C
Oven Temp : 90 °C (hold 1 min) to 330 °C at
8.5 °C/min (hold 5 min)
Carrier Gas : He, constant flow rate 1.4 mL/min
Detector : MS-QP
Transfer Line Temp: 290 °C
Source Temp: 325 °C
Solvent Delay Time: 5 min
Ionization: EI

Pg C-7