Page 159 - Shimadu Consumables Catalog

Capillary Columns
High-Performance Columns

SH-I-5Sil MS
Low-polarity phase: Crossbond™ silarylene phase 1,4-bis(dimethylsiloxy)phenylene
dimethyl polysiloxane SH-I-5Sil MS Structure
Engineered to be a low-bleed GCMS column.
$) $) $)

Excellent inertness for active compounds.
4J 4J 0 4J 0
General-purpose columns—ideal for GCMS analysis of semi-volatiles, polycyclic aromatic
compounds, chlorinated hydrocarbons, phthalates, phenols, amines, organochlorine $) $) $)
pesticides, organophosphorus pesticides, drugs, solvent impurities, and hydrocarbons. Y Z
Similar phases: DB-5ms UI, DB-5ms, VF-5ms, SLB-5ms

For SH-I-5Sil MS columns with Integra-Guard™ column, please refer to page C-44.
ID df Temp. Range 10 m 20 m 40 m 60 m
0.10 mm 0.10 µm -60 to 320/350 °C 227-36317-01 − − −
0.15 µm -60 to 320/350 °C − 227-36030-01 − −
0.15 mm
2.00 µm -60 to 320/350 °C − 227-36031-01 − −
0.10 µm -60 to 320/350 °C − − − 227-36032-01
0.18 mm 0.18 µm -60 to 320/350 °C − 227-36033-01 227-36033-02 −
0.36 µm -60 to 320/350 °C − 227-36034-01 − −
ID df Temp. Range 15 m 30 m 60 m
0.10 µm -60 to 320/350 °C − 227-36035-01 227-36035-02 −
0.25 µm -60 to 320/350 °C − 227-36036-01 221-75954-30 227-36036-02
0.25 mm
0.50 µm -60 to 320/350 °C − 227-36037-01 227-36037-02 −
1.00 µm -60 to 320/350 °C − 227-36038-01 221-75956-30 227-36038-02
0.25 µm -60 to 320/350 °C − 227-36039-01 227-36039-02 −
0.32 mm 0.50 µm -60 to 320/350 °C − − 227-36040-01 −
1.00 µm -60 to 320/350 °C − − 227-36041-01 −
0.53 mm 1.50 µm -60 to 320/330 °C − − 227-36032-02 −

Benzodiazepines
Peaks Conditions
1. Oxazepam Instrument : GCMS-QP2010
2. Lorazepam Column : SH-I-5Sil MS, 30 m, 0.25 mm ID,
3. Diazepam 0.25 μm (P/N: 221-75954-30)
4. Flunitrazepam
5. Prazepam Sample : Diluent: Butyl chloride
6. Clonazepam Conc.: 15 μg/mL
7. Alprazolam Inj. Vol. : 1 μL splitless (hold 1 min)
Inj. Temp : 280 °C
Purge Flow : 32.2 mL/min (20:1 split)
Oven Temp : 200 °C to 330 °C at 15 °C/min
(hold 3 min)
Carrier Gas : He, constant linear velocity mode,
50 cm/sec.
Detector : MS-QP
Transfer Line Temp: 280 °C
Source Temp: 200 °C
Solvent Delay Time: 4 min
Tune: PFTBA
Ionization: EI
Scan Range: 50-350

Pg C-9