Page 153 - Shimadu Consumables Catalog

Structures, polarities, properties, and uses for Shimadzu capillary column phases, in order of increasing polarity
SH-I-1Ms, SH-1HT, SH-I-5Ms, SH-I-5HT, SH-I-5Sil MS SH-20, SH-25
SH-I 1 SH-5, SH-5MS 1,4-bis(dimethylsiloxy)phenylene Diphenyl dimethyl polysiloxane
-
Dimethyl polysiloxane Diphenyl dimethyl polysiloxane dimethyl polysiloxane

Similar to: (5%-phenyl)- Similar to: (5%-phenyl)- Similar to: (20%-phenyl)-
Similar to: (100%-methyl)- methylpolysiloxane Polarity: slightly methylpolysiloxane Polarity: methylpolysiloxane Polarity:
polysiloxane Polarity: nonpolar polar slightly polar slightly polar
Uses: solvents, petroleum products, Uses: flavors, environmental, aromatic Uses: flavors, environmental, Uses: volatile compounds, alcohols
pharmaceutical samples, waxes
hydrocarbons pesticides, PCBs, aromatic
hydrocarbons
SH-1301, SH-624 SH-I-624Sil MS SH-35 SH-I-35Sil MS
Cyanopropylmethyl phenylmethl Diphenyl dimethyl polysiloxane
polysiloxane

Similar to: (35%-phenyl)-
methylpolysiloxane Polarity:
Similar to: (6%-cyanopropylphenyl)- Similar to: (35%-phenyl)- intermediately polar
methylpolysiloxane methylpolysiloxane Uses: pesticides, PCBs, amines,
Polarity: intermediately polar Polarity: intermediately polar
Similar to: (6%-cyanopropylphenyl)- Uses: volatile compounds, insecticides, Uses: pesticides, PCBs, amines, nitrogen-containing herbicides
methylpolysiloxane residue solvents in pharmaceutical nitrogen-containing herbicides
Polarity: intermediately polar products
Uses: volatile compounds,
insecticides
SH-200 SH-50 SH-I-17 SH-I-17Sil MS
Trifluoropropylmethyl polysiloxane Phenyl methyl polysiloxane Diphenyl dimethyl polysiloxane

Similar to: (50%-phenyl)-
methylpolysiloxane Polarity:
Similar to: (50%-phenyl)- intermediately polar
Similar to: (50%-phenyl)-
Similar to: (trifluoropropyl)- methylpolysiloxane Polarity: methylpolysiloxane Uses: triglycerides, phthalate esters,
methylpolysiloxane intermediately polar Polarity: intermediately polar steroids, phenols
Polarity: selective for lone pair Uses: triglycerides, phthalate
electrons Uses: environmental, Uses: FAMEs, carbohydrates esters, steroids, phenols
solvents, Freon® gases, drugs,
ketones, alcohols
SH-1701 SH-65 SH-225 SH-2330
Diphenyl dimethyl polysiloxane Cyanopropylmethyl phenylmethyl Biscyanopropyl cyanopropylphenyl
polysiloxane polysiloxane

Similar to:
(14%-cyanopropylphenyl)- Similar to: (65%-phenyl)-
methylpolysiloxane methylpolysiloxane Polarity: Similar to:
Polarity: intermediately polar intermediately polar (50%-cyanopropylmethyl)-
Uses: pesticides, PCBs, alcohols, Uses: triglycerides, rosin acids, methylphenylpolysiloxane
oxygenates free fatty acids Polarity: polar Similar to: (95%-cyanopropyl)-phenyl
Uses: FAMEs, carbohydrates polysiloxane Polarity: polar
Uses: cis/trans FAMEs, dioxin isomers,
rosin acids
SH-PolarWax, SH-Wax
Polyethylene glycol

**Structures, polarities, and properties also apply to metal MXT® stationary phases.

Polarity: polar
Uses: FAMEs, flavors, acids, amines,
solvents, xylene isomers
Pg C-3