Page 179 - Shimadu Consumables Catalog

Capillary Columns
Dedicated Columns

SH-1614
5% diphenyl / 95% dimethyl polysiloxane
Optimized for PBDE analysis by EPA Method 1614.

Short column option resolves BDE-209 three times faster, with less thermal breakdown.
Unique deactivation gives higher BDE-209 response than competitor columns, for greater analytical sensitivity.
Exceeds EPA Method 1614 resolution criteria for BDE-49 and BDE-71.

ID df Temp. Range 15 m 30 m
0.25 mm 0.10 µm -60 to 330/360 °C 227-36265-01 227-36265-02

Brominated Flame Retardants

Peaks
1. BDE-10 15. BDE-37 29. BDE-126
2. BDE-7 16. BDE-75 30. BDE-154
3. BDE-8 17. BDE-49 31. BDE-153
4. BDE-11 18. BDE-71 32. BDE-138
5. BDE-12 19. BDE-47 33. BDE-166
6. BDE-13 20. BDE-66 34. BDE-183
7. BDE-15 21. BDE-77 35. BDE-181
8. BDE-30 22. BDE-100 36. BDE-190
9. BDE-32 23. BDE-119 37. BDE-208
10. BDE-17 24. BDE-99 38. BDE-207
11. BDE-25 25. BDE-116 39. BDE-206
12. BDE-28 26. BDE-118 40. BDE-209
13. BDE-33 27. BDE-85
14. BDE-35 28. BDE-155

Conditions
Column : SH-1614, 15 m, 0.25 mm ID, 0.10 μm (P/N: 227-36265-01)
Sample : 100-300 ppb PBDE PAR Solution
500 ppb decabromodiphenyl ether
Inj. Vol. : 1 μL splitless (hold 1 min)
Inj. Temp : 340 °C
Carrier Gas : He, constant flow, linear velocity 60 cm/sec., 120 °C
Oven Temp : 120 °C (hold 1 min) to 275 °C at 15 °C/min to 300 °C at 5 °C/min (hold 5 min)
Detector : μ-ECD, 345 °C

Pg C-29