Page 35 - Application Handbook - TOC
P. 35

SCA-130-304



                                                                Initially, a blank value and a control standard
              Compound           Dilution         Conc.         (10 mg/L) were measured, and the NaCl
               (Concen-                                         solution was subsequently injected.
                tration)                                        The control standards  were tested after 110
                 Brine       1 : 2 diluted with    ca.          and 220 injections of the brine solution,
                solution    water (25ml/50ml)     15%ig
                (30%)         add. 1-2 drops                    respectively.
                             Sulfuric acid until
                                  pH<7


            For the analysis a TOC-L CPH equipped with a
            kit for high salt loads was used. The system
            is calibrated using the automated dilution
            function in the range of 0.5 mg/L to 10 mg/L.



                                                                Maintenance of the combustion tube and the
                                                                catalyst was not necessary after the
                                                                measurements were completed. Only the TC-
                                                                slider needed to be cleaned. The figure
                                                                above shows the excellent reproducibility’s
                                                                and the  stability of the measurement.




                        Fig. Multi-point calibration
                          with dilution function

            ■ Result
            The duplicate determination of the TOC
            analysis yielded the following results:


                                   NPOC         RSD
                   Sample
                                    [mg/l]       [%]
             Brine solution (30%)    3,6         1,8
             Brine solution (30%)    3,6         1,8
                                                                ■ Recommended Analyzer / Configuration
            ■ Stability test                                    TOC-L CPH
            In this test, the long-term stability of the        High-Salt-Kit
            combustion  system was tested. The system           B-Type-Scrubber
            was calibrated to 10  mg/L with an injection
            volume of 50 µL.
            A 28% NaCl solution was prepared and
            spiked with a KHP solution to obtain a 5 mg/L
            TOC solution and a 15% sulfuric acid solution
            was added.
   30   31   32   33   34   35   36   37   38   39   40