Page 12 - Shimadzu GCMS-QP2020 NX

Smart Operation

Dramatic Improvement in the Efficiency of Multicomponent Simultaneous Analysis

The efficiency of multi-component simultaneous analysis is dramatically improved thanks to Smart SIM , which Functions Using Retention Indices
™
simplifies and automates the method creation, and LabSolutions Insight software, which greatly reduces the time Automatic Adjustment of Compound Retention Time (AART)
™
needed for analyzing data. C17 C18 C19
Original registered
In addition, databases specialized for specific fields are provided, so regardless of the field in which quantitative The AART (Automatic Adjustment of Retention method information
analysis is to be performed, highly reliable data can be obtained as the result of the optimized analytical Time) function can estimate the retention times of
conditions. target components from retention indices and the 1700 1735 1800 R.I.
retention times of an alkane standard mix*. C17 C18 C19
* Requires alkane mix which is sold separately. Identification
Customer’s Window
More Convenient Multicomponent Analysis Achieved by Smart SIM Instrument
1700 1735 1800 R.I.
The Smart SIM automatic method creation function automatically configures the SIM program to suit the
retention times. Even in cases where there are a number of compounds and they are apportioned to multiple 20 21 22 Retention time
21.1 min 21.5 min Analyte
methods, the methods can be integrated while maintaining the sensitivity as is. This significantly reduces the (Calculated RT) (Originally registered RT)
number of analysis cycles and the measurement time, improving productivity. Automatic Adjustment
Databases Specific to All Kinds of Industries

Databases are available for a variety of GC/MS Forensic Toxicological Database
industries, and contain analysis conditions
optimized for multicomponent batch analysis. Analysis of serum 318.00
The optimal MS table is Analysis can start immediately just by 272.00
233.00
automatically created automatically correcting the retention times
utilizing the AART function.
23.0 23.5
Chlorpromazine
Smart Metabolites 5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0 27.5 30.0 32.5 35.0
Database It is pre-registered with more than 1400 mass spectra including free-, TMS- and TFA-body
Smart SIM types for compounds that are required in forensic toxicological analysis of drugs of abuse,
drugs for psychiatric and neurological disease, and other medicines and pesticides.
Simultaneous Off-Flavor Compound Composer Database Software
Analysis Database Database for Simultaneous Analysis (Environmental Analysis)
Analysis of river water 213
All compound information contained in methods for currently used Shimadzu GC/MS systems can be stored in the
database simply by selecting the files. Forensic Toxicology Quick-DB
Database Pesticide Database
26.00 26.50
Bisphenol A

5.0 7.5 10.0 12.5 15.0 17.5 20.0 22.5 25.0 27.5 30.0 32.5 35.0
Simultaneous GC/MS analysis supporting identification and quantification of 942
environmental pollutants can be performed.
The retention times and calibration curve information of environmentally hazardous
chemical substances are registered, so approximate concentrations can be obtained, even
when it is difficult to obtain standards.
Quantitation Analysis Without Using Standard Samples

™
Quick-DB GC/MS Residual Pesticides Database is preregistered with calibration curves created utilizing pesticide
High-sensitivity, high-accuracy analysis is enabled in comparison to the group measurement method. In a batch surrogates, enabling quantitative analysis without having to create methods using standards. A total of 474 components
analysis of 434 components, favorable repeatability and calibration curves were obtained, even down to the (for scan or SIM mode) are contained in the database, enabling the comprehensive quantitative analysis of pesticides.
trace-quantity region, improving quantitative performance.
(Compound Composer Database Software and GC/MS Forensic Toxicological Database also contain this function.)
Conventional Method
Smart SIM Y = 8320.518X − 2899.459 (Group Measurement) Y = 7547.102X − 26544.7
R^2 = 0.999566 R^2 = 0.9921897 Calibration curves of the relative ratio of
1 (#1) Zoxamide R = 0.999783 1 (#1) Zoxamide R = 0.9960872 Intensity Internal Intensity internal standard substances are
1 (#2) 2 ppb Average RF: 8604.262 1 (#2) 2 ppb Average RF: 6020.259 Standard
1 (#3) %RSD = 2.4% RF SD: 1,424.947 1 (#3) %RSD = 24.9% RF SD: 1,293.612 Pesticide Substance Internal preregistered. A semi-quantitative value is
1 (#4) (n = 6) RF %RSD: 16.56094 1 (#4) RF %RSD: 21.48766 Pesticide Standard acquired by adding an internal standard to a
1 (#5) Area 1 (#5) (n = 6) Area Substance
1 (#6) 800000 1 (#6) 700000 sample. If accurate quantitative values are
700000 600000
600000 500000 required, be sure to quantify them using a
500000 conventional method.
400000 400000
300000 300000
200000 200000 Ratio on Database Ratio on Actual Instrument
100000 100000
0 0
17.3 17.4 17.5 17.6 17.7 17.8 0 10 20 30 40 50 60 70 80 90 Conc. 17.2 17.3 17.4 17.5 17.6 17.7 0 10 20 30 40 50 60 70 80 90 Conc. (Tolclofos-methyl: 10 ng/mL)
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