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 Shimadzu Equipment for Evaluating Lithium-ion Rechargeable Batteries
 Electrodes         How the Lithium-ion Rechargeable Battery Works




 Active Materials                                                 Binder

 ICP Emission Spectrometer  Sequential X-Ray Fluorescence Spectrometer  High-Performance Liquid Chromatograph
 ICP Series  LAB CENTER XRF-1800  Prominence Series

 Offers highly sensitive and accurate compositional analysis of materials and parts,   Permits the non-destructive qualitative analysis of elements in different sample   Prominence allows the separation and quantitation of organic substances and ions contained in the electrolyte
 such as electrodes and electrolyte solution.   states – solid, powder, or liquid. The FP method can conduct quantitative analysis   solution.
 An extensive lineup, from a multi-type system that features low running costs and   without a calibration curve. It simplifies quantitation of battery constituent   The extensive product range supports a wide range of analysis from ppb level to percentage level. In addition
 quickly analyze.  materials from major components to impurities, and provides comprehensive   to concentration measurements, these instruments can measure the molecular weight distribution of polymers.
 applications, including measurement of minute, 500 µm diameter regions.


 Int.(Intensity)      Infrared Microscope Measurement System             Scanning Probe Microscope

                      IRTracer-100                                       SPM-9700HT
 WL(Wavelength)     Effective for the composition analysis of binders, electrolytes, and separators.   The SPM-9600 easily takes high-magnification 3D images in air or liquid for
 Spectral Line Profile  The ATR method virtually eliminates the need for pretreatment and permits   surface observations of samples from electrodes and semiconductors to separators
                    analysis of microscopic regions of a sample surface or thin film. The accuracy and   and electrolyte membranes. Non-conductive objects do not  require coating or
                    operability of the microscope system has been enhanced.  other pretreatment. The instrument can measure the electrical characteristics of
 Electron Probe Microanalyzer  Nano Particle Size Analyzer             the sample at the probe tip. Upgradeable to environment-controlled SPM.

 EPMA-8050G  SALD-7101
 This instrument allows dispersion confirmation of the positive electrode materials   Allows particle size distribution measurements in positive and negative active materials.
 and observation of the distributions of binder and conduction enhancer. It can   The SALD-7101 combines laser diffraction and scattering methods with a UV
 also evaluate the deterioration of fuel cells by observing the behavior of fluorine in   semiconductor laser (375 nm wavelength) to measure particle size distributions from
 the solid polymer. The EPMA-8050G incorporates a high-resolution electron source   10 nm to 300 µm. Comprehensive options are available, including a high-concentration
 for evaluation of the minute amounts of catalyst on the electrodes.  sample measuring system and software to acquire data at 1 second intervals.






                                              Electrolyte Solution (Solvent, Electrolyte, Additive)

                      Gas Chromatograph - Mass Spectrometer              Gas Chromatograph

 X-ray Diffractometer  GCMS-QP2020                                       GC-2010Plus/2014 Series
 Gr Group: LIB, Data: Positive electrode material
 ode material
 oup: LIB, Data: Positive electr
 XRD-6100           This instrument is effective for composition analysis of electrolyte membranes,   These instruments offer highly accurate and sensitive analysis of evolved gases
                    separators, and solvents in the electrolyte solution as well as for component   and electrolytes. The GC-2010Plus/2014 supports both packed and capillary
 X-ray diffractometry allows the qualitative analysis of crystalline   analysis of emitted gases.   columns to analyze a diverse range of samples. Excellent repeatability is
 compounds. It can analyze the crystalline structure, orientation,   In combination with pyrolysis, headspace, or other pretreatment methods, the   assured by the optimized sample injection unit and the electronic flow
 and size of positive and negative electrode active materials in the   GCMS-QP2020 can analyze samples in different states. In addition to the   controller (AFC) that accurately controls the carrier gas up to the
 battery. It also offers qualitative analysis, crystallinity analysis, and   commonly used electrospray ionization (EI), negative chemical ionization (NCI) is   high-pressure, high-flow rate regions required for fast analysis.
 orientation analysis of the separator material. Highly sensitive   Diffraction Patterns of Positive Electrode Material   available as an option to perform highly sensitive and selective analysis.
 analysis using the polycapillary optical system is also possible.  in a Lithium-ion Rechargeable Battery

 KRATOS AXIS-Supra Imaging XPS System

 AXIS-Supra
 Permits observations of the composition and chemical status of materials on
 the electrode and separator surfaces at nanometer-order resolution in the
 depth direction. The XPS system can conduct measurements without
 pretreatment, irrespective of the sample conductivity. It is effective for
 evaluating materials characteristics and the degree of surface contamination.

                                                            Rechargeable Lithium-Ion Battery Evaluation
 4                                                                                    Analytical and Measuring Instruments for Rechargeable Lithium-ion Batteries  5
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