Page 17 - Shimadzu Nexis GC-2030
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Petrochemical  Monitoring Sulfur in Diesel Oil Distillates

               Using a detector splitting device with minimal dead volume, it is possible to analyze the components in diesel oil comprehensively
 Refinery Gas Analysis System  2  3  [FID]  with MS, while simultaneously measuring* the sulfur components selectively and with high sensitivity using an SCD.
 +
 1.  C 6
 6  2.  Methane
 Specialized systems can be con gured by installing multiple   8  13  3.  Ethane
 valves and columns in the standard Nexis GC-2030 installation   4  5  17 18  4.  Ethylene  MS(TIC)
 5.  Propane
 space. Inorganic gases, hydrocarbons, hydrogen sul des, and   7  11 12 14  21  22  6.  Propylene
 7.  Isobutane
 other components can be analyzed within  ve and a half   1  9  10  15 16  19 20  8.  n-Butane
 minutes. Method development is not required because systems   9.  Propadien
 10. Acetylene
 are assembled and tested in advance at the factory, prior to   0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min 11. trans-2-Butene
 12. 1-Butene
 arriving at your lab.  Re nery Gas Analysis (FID)  13. i-Butene
 14. cis-2-Butene
 15. Isopentane
 29  30  16. n-Pentane
 17. 1,3-Butadien
 18. Methylacetylene
 19. trans-2-Pentene
 28  20. 2-Methyl-2-butene
 21. 1-Pentene
 23  26  27  22. cis-2-Pentene  SCD
 25
 24  31  [TCD-1]
 23. Carbon dioxide
                                                                                             ™
 24. Ethylene                                                       GCMS-QP2020 NX + SCD-2030 + AOC -30i
 0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min 25. Ethane  Di-tert-butyl disulfide
 26. Acetylene
 Re nery Gas Analysis (TCD-1)  27. Hydrogen sul de
 28. Oxgen                                                    * LabSolutions DB GCMS or LabSolutions CS is required to acquire data
 29. Nitrogen
 30. Methane                                                     simultaneously from a GCMS and SCD.
 31. Carbon Monoxide
 32  [TCD-2]
 32. Hydrogen        Simultaneous Analysis of Sulfur Standard
                    Components in Diesel Using GC-MS and SCD
 0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min
 Re nery Gas Analysis (TCD-2)
               Environment                                       Xylenes
                                                  Acetonitrile  Toluene
               Analysis of VOCs in                             Ethylbenzene
 Analysis of Simulated Distillation  Work Environments
 Simulated Distillation GC Analysis Software integrated with   Trace components in the air can be
 LabSolutions is compliant with ASTM, ISO, and various other   concentrated for measurement via thermal   Hexane  Standard
                                                                    sample
 standards that specify distillation GC. With high boiling point   desorption. The TD-30 can accommodate   100 ng
 compounds, sample loss can be minimized by using the   up to 120 samples, and thanks to the   Room air
 OCI-2030 NX injection port.
               repeated collection function, if a precious   2.0  3.0  4.0  5.0  6.0  min
               sample is analyzed incorrectly, it can be   Analysis of VOCs in Work Environments  Nexis  GC-2030 + TD-30
                                                                                     ™
               measured again.
 Compatibility with Simulated
 Distillation GC Analysis Software  Simulated Distillation GC Analysis Software
               Coordinating with
 Carbon number  Sample
 ASTM D 3710,D 7096  n-C3 to n-C15  Gasoline, naphtha  Compatible Products
 JIS K 2254  -  Kerosene, diesel
 ASTM D 2887 (ISO3924, IP406)  n-C5 to n-C44  Jet fuel, diesel
               By coordinating with other brands of
 ASTM D 6417  n-C8 to n-C60  Lubricant oil, base oil
               pretreatment systems, detectors, and
 ASTM D 7213(Extended D2887)  n-C7 to n-C60  Lubricant oil, base oil
               analysis software, an application system
 ASTM D 6352  n-C10 to n-C90  Lubricant oil, base oil
               can be constructed that is compatible
 ASTM D 7500   n-C7 to n-C100  Lubricant oil, base oil  with various standards, methods, and
 EN 15199-1 (IP480, DIN 51435)  n-C7 to n-C120  Lubricant oil, base oil  regulations.
 ASTM D 5307          to n-C44  Crude oil (internal standard method)  Examples: MOSH/MOAH analysis; PIONA
               analysis; analysis of VOCs in water;
 Crude oil (external standard method,
 ASTM D 7169, EN 15199-2 (IP 507)  n-C7 to n-C100  up to n-C120 for EN)
 Chromatogram of Polywax (ASTM D 7500)  analysis of gases produced by high
               polymer materials; and analysis of    AOC -6000 Plus               EGA/PY-3030D Pyrolizer
                                                        ™
 * Please contact Shimadzu representatives for
    more details of compatibility   phthalate esters in flame retardants.  Multifunctional Autosampler  (Frontier Laboratories)
 16                                                                                                    Gas Chromatograph  17
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