Page 16 - Shimadzu Nexis GC-2030
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Petrochemical                                                                                                      Monitoring Sulfur in Diesel Oil Distillates

                                                                                                                                        Using a detector splitting device with minimal dead volume, it is possible to analyze the components in diesel oil comprehensively
                     Refinery Gas Analysis System                        2  3                          [FID]                            with MS, while simultaneously measuring* the sulfur components selectively and with high sensitivity using an SCD.
                                                                                                         +
                                                                                                       1.  C 6
                                                                                   6                   2.  Methane
                     Specialized systems can be con gured by installing multiple      8    13          3.  Ethane
                     valves and columns in the standard Nexis GC-2030 installation   4  5      17 18   4.  Ethylene                      MS(TIC)
                                                                                                       5.  Propane
                     space. Inorganic gases, hydrocarbons, hydrogen sul des, and    7    11 12 14  21  22  6.  Propylene
                                                                                                       7.  Isobutane
                     other components can be analyzed within  ve and a half   1       9 10   15 16  19 20  8.  n-Butane
                     minutes. Method development is not required because systems                       9.  Propadien
                                                                                                       10. Acetylene
                     are assembled and tested in advance at the factory, prior to   0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min 11. trans-2-Butene
                                                                                                       12. 1-Butene
                     arriving at your lab.                                  Re nery Gas Analysis (FID)  13. i-Butene
                                                                                                       14. cis-2-Butene
                                                                                                       15. Isopentane
                                                                                      29  30           16. n-Pentane
                                                                                                       17. 1,3-Butadien
                                                                                                       18. Methylacetylene
                                                                                                       19. trans-2-Pentene
                                                                                     28                20. 2-Methyl-2-butene
                                                                                                       21. 1-Pentene
                                                                          23   26  27                  22. cis-2-Pentene                 SCD
                                                                            25
                                                                           24                    31    [TCD-1]
                                                                                                       23. Carbon dioxide
                                                                                                                                                                                                                      ™
                                                                                                       24. Ethylene                                                                           GCMS-QP2020 NX + SCD-2030 + AOC -30i
                                                                    0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min 25. Ethane            Di-tert-butyl disulfide
                                                                                                       26. Acetylene
                                                                           Re nery Gas Analysis (TCD-1)  27. Hydrogen sul de
                                                                                                       28. Oxgen                                                                        * LabSolutions DB GCMS or LabSolutions CS is required to acquire data
                                                                                                       29. Nitrogen
                                                                                                       30. Methane                                                                         simultaneously from a GCMS and SCD.
                                                                                                       31. Carbon Monoxide
                                                                                                32     [TCD-2]
                                                                                                       32. Hydrogen                            Simultaneous Analysis of Sulfur Standard
                                                                                                                                              Components in Diesel Using GC-MS and SCD
                                                                    0.0  0.5  1.0  1.5  2.0  2.5  3.0  3.5  4.0  4.5  5.0  min
                                                                           Re nery Gas Analysis (TCD-2)
                                                                                                                                        Environment                                        Xylenes
                                                                                                                                                                            Acetonitrile  Toluene
                                                                                                                                        Analysis of VOCs in                              Ethylbenzene
                     Analysis of Simulated Distillation                                                                                 Work Environments
                     Simulated Distillation GC Analysis Software integrated with                                                        Trace components in the air can be
                     LabSolutions is compliant with ASTM, ISO, and various other                                                        concentrated for measurement via thermal   Hexane    Standard
                                                                                                                                                                                              sample
                     standards that specify distillation GC. With high boiling point                                                    desorption. The TD-30 can accommodate                 100 ng
                     compounds, sample loss can be minimized by using the                                                               up to 120 samples, and thanks to the                 Room air
                     OCI-2030 NX injection port.
                                                                                                                                        repeated collection function, if a precious   2.0  3.0  4.0  5.0  6.0  min
                                                                                                                                        sample is analyzed incorrectly, it can be   Analysis of VOCs in Work Environments  Nexis  GC-2030 + TD-30
                                                                                                                                                                                                               ™
                                                                                                                                        measured again.
                     Compatibility with Simulated
                     Distillation GC Analysis Software                    Simulated Distillation GC Analysis Software
                                                                                                                                        Coordinating with
                                       Carbon number  Sample
                      ASTM D 3710,D 7096  n-C3 to n-C15  Gasoline, naphtha                                                              Compatible Products
                      JIS K 2254          -     Kerosene, diesel
                      ASTM D 2887 (ISO3924, IP406)  n-C5 to n-C44  Jet fuel, diesel
                                                                                                                                        By coordinating with other brands of
                      ASTM D 6417       n-C8 to n-C60  Lubricant oil, base oil
                                                                                                                                        pretreatment systems, detectors, and
                      ASTM D 7213(Extended D2887)  n-C7 to n-C60  Lubricant oil, base oil
                                                                                                                                        analysis software, an application system
                      ASTM D 6352      n-C10 to n-C90  Lubricant oil, base oil
                                                                                                                                        can be constructed that is compatible
                      ASTM D 7500      n-C7 to n-C100  Lubricant oil, base oil                                                          with various standards, methods, and
                      EN 15199-1 (IP480, DIN 51435)  n-C7 to n-C120  Lubricant oil, base oil                                            regulations.
                      ASTM D 5307              to n-C44  Crude oil (internal standard method)                                           Examples: MOSH/MOAH analysis; PIONA
                                                                                                                                        analysis; analysis of VOCs in water;
                                                Crude oil (external standard method,
                      ASTM D 7169, EN 15199-2 (IP 507)  n-C7 to n-C100  up to n-C120 for EN)
                                                                          Chromatogram of Polywax (ASTM D 7500)                         analysis of gases produced by high
                                                                                                                                        polymer materials; and analysis of     AOC -6000 Plus              EGA/PY-3030D Pyrolizer
                                                                                                                                                                                  ™
                     * Please contact Shimadzu representatives for
                        more details of compatibility                                                                                   phthalate esters in flame retardants.  Multifunctional Autosampler  (Frontier Laboratories)
        16                                                                                                                                                                                                                       Gas Chromatograph  17
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